When referring to the Spectral Atlas, please cite our publication:
Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen,
R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of
atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013),
DOI: 10.5194/essd-5-365-2013
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DATAFILE: | OClO_Burkholder(1990)_298K_240.2-339.5nm.txt |
NAME: | chlorine dioxide |
FORMULA: | OClO |
AUTHOR(YEAR): | Burkholder(1990) |
T: | 298K |
λ: | 240.2-339.5nm |
BIBLIOGRAPHY: |
J.B. Burkholder, J.J. Orlando, and C.J. Howard, "Ultraviolet absorption cross section of Cl2O2 between 210 and 410 nm",
J. Phys. Chem. 94, 687-695 (1990);
DOI: 10.1021/j100365a033
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COMMENTS: | Discharge flow tube reactor coupled to a to a multipass absorption cell and a diode array spectrometer (spectral resolution ∼1.2 nm)
The transient CI2O2 molecule was produced by using the gas-phase reaction CIO + CIO + M → Cl2O2 + M, and three independent CIO radical source reactions, CI + O3, CI + CI2O, and CI + OCIO were used
The OClO reference spectrum depicted in Fig. 3 has been digitized |
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